Since most high-temperature materials are optimized with regard to strength and corrosion resistance at elevated temperatures, their resistance to electrochemical low-temperature corrosion may be less satisfactory. Components made of high-temperature material should therefore be designed and operated so that acid condensates are not formed, or at least so that any such condensates are drained away.
The resistance of a material to high-temperature corrosion is in many cases dependent on its ability to form a protective oxide layer. In a reducing atmosphere, when such a layer cannot be created (or maintained), the corrosion resistance of the material will be determined by its alloy content.
When a material is exposed to an oxidizing environment at elevated temperatures, a more or less protective oxide layer will be formed on its surface. Even if oxidation is seldom the primary cause of high-temperature corrosion failures, the oxidation behavior is important, because the properties of the oxide layer will determine the resistance to attack by other aggressive elements in the environment.The oxide growth rate increases with increasing temperature until the rate of oxidation becomes unacceptably high or until the oxide layer begins to crack and spall off, i.e. the scaling temperature is reached. The alloying elements that are most beneficial for oxidation resistance are chromium, silicon, and aluminum. A positive effect has also been achieved with small additions of so-called (re)active elements, e.g. yttrium, hafnium, and rare earth metals (REM, e.g. Ce and La). These affect the oxide growth so that the formed layer will be thinner, tougher, and more adherent, and thus more protective. This is especially beneficial in conditions with varying temperatures.
PRE Pitting Resistant Equivalent calculated using the formula: PRE = %Cr + 3.3 x %Mo + 16 x %N
CPT Corrosion Pitting Temperature as measured in the Avesta Cell (ASTM G 150), in a 1M NaCl solution (35,000 ppm or mg/l chloride ions).
CCT Critical Crevice Corrosion Temperature is the critical crevice corrosion temperature which is obtained by laboratory tests according to ASTM G 48 Method F