Outokumpu grade 4420 has excellent corrosion resistance in solutions of many halogen-free organic and inorganic compounds over a wide temperature and concentration range. It can withstand many organic and diluted mineral acids depending on the temperature and concentration of the solution. Grade 4420 may suffer from uniform corrosion in strong mineral acids and hot strong alkaline solutions.
In aqueous solutions containing halogenides like e.g. chlorides or bromides, pitting and crevice corrosion may occur depending on halogenide concentration, temperature, pH-value, concentration of oxidizing compounds and crevice geometry, if applicable. Due to its high chromium and nitrogen content, the pitting and crevice corrosion resistance of grade 4420 is on the same level or even better than the corrosion resistance of the austenitic CrNiMo standard grades 4401 and 4404 despite its lower molybdenum content. The presence of corrosion inhibiting or accelerating compounds like e.g. transition metal ions or organic compounds may influence the corrosion behaviour of grade 4420.
Grade 4420 is prone to chloride-induced stress corrosion cracking at temperatures over about 50°C depending on the applied stress and the chloride concentration in the environment. Prior cold deformation of the structure under load increases the risk for stress corrosion cracking.
Grade 4420 can be used for indoor and outdoor applications in urban and moderately corrosive industrial environments. When chloride contamination may be high like for instance in coastal areas, pitting and staining is possible. The best material performance is reached usually with the help of adequate design, correct post-weld treatment and regular cleaning during use (if applicable).
For more information on corrosion resistance refer to the Outokumpu Corrosion Handbook or contact the Outokumpu corrosion experts.
PRE Pitting Resistant Equivalent calculated using the formula: PRE = %Cr + 3.3 x %Mo + 16 x %N
CPT Corrosion Pitting Temperature as measured in the Avesta Cell (ASTM G 150), in a 1M NaCl solution (35,000 ppm or mg/l chloride ions).
CCT Critical Crevice Corrosion Temperature is the critical crevice corrosion temperature which is obtained by laboratory tests according to ASTM G 48 Method F