In oxidising environments, a protective oxide layer is likely to be formed on the metallic surface. If the layer is tight and adherent, it can prevent other aggressive elements in the environment from attacking and reacting with the steel. However, the layer can grow in thickness due to constant oxidation. The resulting porous layer will allow the gas to penetrate through to the base material through pores or cracks. Silicon and aluminum are both beneficial for oxidation resistance. Low thermal expansion and high thermal conductivity of the ferritic base material reduce changes in volume and thus spalling of the protective layer.
As a rule, ferrites perform better than austenites in oxidising and reducing sulphurous atmospheres. SO2 or H2S are possible compounds in sulphur containing process gases or fuels. In terms of resistance to carburisation, austenitic grades show more favorable results than ferritic ones due to their high Ni-content. Formation of chromium carbides or chromium nitrides, respectively, embrittles the material. Additionally, the surrounding matrix becomes chromium depleted and thus less able to form an oxide layer, which consequently reduces the scaling resistance of the material. Silicon has a beneficial effect on both carbon and nitrogen pick-up. Aluminum is only favorable in terms of carburisation. The high nitrogen affinity of aluminum results in aluminum nitrides retarding formation of a protective alumina and leading to premature failure of the material.
In molten metals, Nickel is the most susceptible element to dissolution. Austenitic material is bound to fail when e.g. molten copper penetrates the grain boundaries. HT ferrites - on the other hand - are expected to show good compatibility with molten copper. Final resistance will, of course, depend on the composition of the molten metal.
For more information, see Outokumpu Corrosion Handbook.
PRE Pitting Resistant Equivalent calculated using the formula: PRE = %Cr + 3.3 x %Mo + 16 x %N
CPT Corrosion Pitting Temperature as measured in the Avesta Cell (ASTM G 150), in a 1M NaCl solution (35,000 ppm or mg/l chloride ions).
CCT Critical Crevice Corrosion Temperature is the critical crevice corrosion temperature which is obtained by laboratory tests according to ASTM G 48 Method F